state and explain hess,s law of constant heat summation with suitable example.what are it,s application
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Explanation:
It states that
"Overall the enthalpy change for a reaction is equal to sum of enthalpy changes of individual steps in the reaction".
Ex:
- 2H2 + N2 gives N2H4. ∆H=+95.4KJ
- N2H4 + H2 gives 2NH3. ∆H=-187.6KJ
3H2 +H2 gives 2NH3. ∆H=-92.2KJ---eqn3
eqn3 gives total enthalpy change of reaction.
APPLICATION:
The Hess's law has been usefull to calculate the enthalpy changes for the reactions with their enthalpies being not known experimentally.
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