state and explain marconic of rule?
Answers
The Markownikoff rule states that when a halogen acid (acids containing halogen) like HCl, HBr etc reacts with double bond containing compound then the negative part of acid ( Cl, Br etc) connects to those carbon atom having less number of Hydrogen.
Example :-
Reaction of 1 propene with HCl.
CH2=CH-CH3 + HCl - - > CH3 +
CH3-CH2Cl.
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Answer:
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The rule states that with the addition of a protic acid HX to an asymmetric alkene, the acid hydrogen (H) gets attached to the carbon with more hydrogen substituents, and the halide (X) group gets attached to the carbon with more alkyl substituents. Alternatively, the rule can be stated that the hydrogen atom is added to the carbon with the greatest number of hydrogen atoms while the X component is added to the carbon with the least number of hydrogen atoms.[3]
The rule states that with the addition of a protic acid HX to an asymmetric alkene, the acid hydrogen (H) gets attached to the carbon with more hydrogen substituents, and the halide (X) group gets attached to the carbon with more alkyl substituents. Alternatively, the rule can be stated that the hydrogen atom is added to the carbon with the greatest number of hydrogen atoms while the X component is added to the carbon with the least number of hydrogen atoms.[3]The same is true when an alkene reacts with water in an addition reaction to form an alcohol which involve formation of carbocations. The hydroxyl group (OH) bonds to the carbon that has the greater number of carbon–carbon bonds, while the hydrogen bonds to the carbon on the other end of the double bond, that has more carbon–hydrogen bonds.
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