state roults law for a sodium containing non voletile solute desolve in voletile solvent
Answers
Answer:
The vapour pressure of a solution of a non-volatile solute is equal to the vapour pressure of the pure solvent at that temperature multiplied by its mole fraction.
In equation form:
pT=pB0.χB
In this equation, pB0 is the vapour pressure of the pure solvent at a particular temperature, pT is the total pressure of the solution, χB is the mole fraction of the solvent.
For a solution of a volatile solute (A) and solvent (B) total pressure is sum of the partial pressure of the two as:
pT=pA0.χA+pB0.χB
As χA++χB=1 or χA=1−χB
or pT=pA0.(1−χB)+pB0.χB
pT=pA0+(pB0−pA0).χB
For non-volatile solute pA0=0
thus pT=pB0.χB
Limitations of Raoult's law:
1. Intermolecular forces between the solvent and solute components shoul be similar to those betweenindividual molecules
A_A=B-B=A-B
2. The gaseous phase are assumed to behave ideal where ideal gas law can be applied.
Answer:
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