Stork enamine reaction in organic synthesis
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The Stork enamine alkylation, involves the addition of an enamine to an alpha, beta-unsaturated carbonyl acceptor in a process similar to the Michael reaction.[1] The product is then hydrolyzed by an aqueous acid to produce a 1,5-dicarbonyl compound.
The process:
formation of an enamine from a ketone
addition of the enamine to an alpha, beta-unsaturated aldehyde or ketone
hydrolysis of the enamine back to a
The process:
formation of an enamine from a ketone
addition of the enamine to an alpha, beta-unsaturated aldehyde or ketone
hydrolysis of the enamine back to a
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