Sugars that differ with respect to configuration around one specific carbon atom are
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When two sugars differ only in the configuration around one carbon atom, they are called epimers of each other; D-glucose and D-mannose, which differ only in the stereochemistry at C-2, are epimers, as are D-glucose and D-galactose (at C-4) (Fig. 11-4).
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Epimers
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