Suppose in an atom electrons are present in three different orbitals 3p, 5d and 5s.
Arrange these electrons in there orbitals in increasing order of effective nuclear charge
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There is only one way in which a sphere (l = 0) can be oriented in space. Orbitals that have polar (l = 1) or cloverleaf (l = 2) shapes, however, can point in different directions. We therefore need a third quantum number, known as the magnetic quantum number (m), to describe the orientation in space of a particular orbital. (It is called the magnetic quantum number because the effect of different orientations of orbitals was first observed in the presence of a magnetic field.)
Explanation:
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Order or shielding effect is s>p>d>f.
Explanation:
This is because s is near to nucleus, so it will shield more the nuclear charge.
As Z
eff
=Z−shielding constant
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