Surface Chemistry Adsorption Isotherms
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Explanation:
Freundlich Adsorption Isotherm
x/m = K [P^(1/n)]
‘x’ is mass of adsorbate on the mass of adsorbent
⇒ log K/m = 1/n (log P + log K)
It does not apply for the adsorption of gases on solids at a higher pressure
Langmuir Adsorption Isotherm
- The layer of gas adsorbed on the solid adsorbent is one-molecule thick.
- The adsorbed layer is uniform all over the adsorbent.
- There is no interaction between the adjacent adsorbed molecules.
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