Chemistry, asked by luckybadgujar9ovpgsr, 1 year ago

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Answered by Alleei
1

Answer : The correct option is, (2) -150 R

Explanation :

As we know that,

Heat released at constant pressure is known as enthalpy.

Heat released at constant volume is known as internal energy.

The given balanced chemical reaction is,

\frac{1}{8}S_8(s)+\frac{3}{2}O_2(g)\rightarrow SO_3(g)

Formula used :

\Delta H=\Delta U+\Delta n_gRT

or,

\Delta H-\Delta U=\Delta n_gRT

where,

\Delta H = heat change at constant pressure

\Delta U = heat change at constant volume

\Delta n_g = change in moles = [(1mol)-(3/2mol)] = -0.5 mole

R = gas constant  

T = temperature = 27^oC=273+27=300K

Now put all the given values in the above formula, we get:

\Delta H-\Delta U=\Delta n_gRT

\Delta H-\Delta U=(-0.5mole)\times (300K)\times R

\Delta H-\Delta U=-150R

Therefore, the difference between the heat change at constant pressure and volume will be, -150 R.

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