☞what is hyperconjugation..?
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In organic chemistry, hyperconjugation (or σ-conjugation) refers to the delocalization of electrons with the participation of bonds of primarily σ-character.
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- In the formalism that separates bonds into σ and π types, hyperconjugation is the interaction of σ-bonds (e.g. C-H, C-C, etc.)
- The interaction between filled π or p orbitals and adjacent antibonding σ* orbitals is referred to as "negative hyperconjugation".
Example:-
- fluoroethyl anion: RADOM (1982).
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