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option b If there is bonding between two atoms where one atom is having one vacant orbital and another is having one lone pair of electrons, then if this electron pair is donated to that respective vacant orbital then the bonding is called p(pie) - p(pie) or p(pie) - d(pie) depending on the orbital to which the electron pair is donated and from which the electron pair is donated.
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Option A
Th tendency to form pi bond increases in the order
SiO<PO<SO<ClO
Since the size of Cl tom is smaller compared to Si, P and S, in case of Cl, less internuclear distance results in more effective sideways overlapping.
With increase in the tendency to form the pi bond, the tendency for polymerization decreases.
Hence, the decreasing order for the tendency for polymerization is SiO4>PO4>SO4>ClO4.
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