Chemistry, asked by Braɪnlyємρєяσя, 4 months ago



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Answered by ItzPerfectLover
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Question:

Phenol and water are partially miscible liquids. By mixing these two phases in equilibrium.Find the number of degrees of freedom of the system and mention them with the helps of its phase Diagram.

Answer:

As suggested by the Gibbs Phase Rule, the most important variables describing a mixture are pressure, temperature and composition. In the case of single component systems, composition is not important so only pressure and temperature are typically depicted on a phase diagram. However, for mixtures with two components, the composition is of vital important, so there is generally a choice that must be made as to whether the other variable to be depicted is temperature or pressure.Temperature-composition diagrams are very useful in the description of binary systems, many of which will for two-phase compositions at a variety of temperatures and compositions. In this section, we will consider several types of cases where the composition of binary mixtures are conveniently depicted using these kind of phase diagrams.Partially Miscible Liquids A pair of liquids is considered partially miscible if there is a set of compositions over which the liquids will form a two-phase liquid system. This is a common situation and is the general case for a pair of liquids where one is polar and the other non-polar (such as water and vegetable oil.) Another case that is commonly used in the organic chemistry laboratory is the combination of diethyl ether and water. In this case, the differential solubility in the immiscible solvents allows the two-phase liquid system to be used to separate solutes using a separatory funnel method.

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Answered by poojamanjrekar1972
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Diagram:

Refers to the attachment

Question:

Phenol and water are partially miscible liquids. By mixing these two phases in equilibrium.Find the number of degrees of freedom of the system and mention them with the helps of its phase Diagram.

Answer:

As suggested by the Gibbs Phase Rule, the most important variables describing a mixture are pressure, temperature and composition. In the case of single component systems, composition is not important so only pressure and temperature are typically depicted on a phase diagram. However, for mixtures with two components, the composition is of vital important, so there is generally a choice that must be made as to whether the other variable to be depicted is temperature or pressure.Temperature-composition diagrams are very useful in the description of binary systems, many of which will for two-phase compositions at a variety of temperatures and compositions. In this section, we will consider several types of cases where the composition of binary mixtures are conveniently depicted using these kind of phase diagrams.Partially Miscible Liquids A pair of liquids is considered partially miscible if there is a set of compositions over which the liquids will form a two-phase liquid system. This is a common situation and is the general case for a pair of liquids where one is polar and the other non-polar (such as water and vegetable oil.) Another case that is commonly used in the organic chemistry laboratory is the combination of diethyl ether and water. In this case, the differential solubility in the immiscible solvents allows the two-phase liquid system to be used to separate solutes using a separatory funnel method.

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