The best method of prepration of alkayl fluoride is
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Alkyl fluorides can be prepared by action of mercurous fluoride or antimony trifluorides (inorganic fluorides) on corresponding alkyl halide. This reaction is known as Swarts reaction. CH3Br+AgF→CH3FMethylfluoride+AgBr But, when aciton of Nal/acetone takes place on alkyl chloride of bromide alkyl iodide forms.
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The synthesis of alkyl fluorides is best accomplished by Swarts reaction.
Alkyl bromides or alkyl chlorides are heated in presence of metallifluorides such as AgF,CoF
2
,SbF
5
orHg
2
F
2
to obtain alkyl fluorides.
CH
3
−Cl+AgF→CH
3
−F+AgCl
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