the boiling point of solution containing 6.62g of substance A in 100g of water is higher by 0.0512°C then the boiling point of pure water, the molar mass of substance is?
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Given info : the boiling point of solution containing 6.62g of substance A in 100g of water is higher by 0.0512°C then The boiling point of pure water.
To find : the molar mass of substance is ..
solution : change in boiling point, ∆Tb = 0.0512°C
mass of water (solvent) = 100g
mass of substance A (solute) = 6.62 g
we know, ∆Tb = Kb × m
for water, ebulioscopic constant, Kb = 0.512 k kg/mol
∴ 0.0512 = 0.512 × m
⇒ m = 0.1
m is molality so m = no of moles of substance A/mass of solvent in kg
⇒0.1 = (6.62/M)/(100/1000)
⇒0.1 = 66.2/M
⇒M = 662 g/mol
Therefore the molar mass of substance A is 662 g
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