the bond dissociation energies of X2 Y2 and xy are in the ratio of 1:0.5:1delta H for the formation of xy is - 200kj the bond dissociation energies of X2 will be
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Bond dissociation energy: The energy measure of a chemical bond A–B is defined as bond dissociation energy.
Energy is the enthalpy change when the bond A–B is separated by homolysis to give two fragments A and B.
Given:
Energy of x2 = 1
Energy of y2 = 0.5
Energy of xy = 1
ΔH for xy = -200KJ
Solution:
x2 + y2 -> 2xy
ΔH is given by Bond energy
So,
Bond energy (x-y) = a
Bond energy (x-x) = a
Bond energy (y-y) = a/2
ΔH f(x-y) = -200KJ
Therefore,
-400KJ for 2 moles
-400 = -a/2
a = 800KJ
Hence, the bond dissociation energies of X2 will be 800 KJ per mole.
anamarshi:
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