Chemistry, asked by prasadadange, 2 months ago

The chemical potential is a fundamental parameter in thermodynamics and it is conjugate to the​

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Answered by piyush433062
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Explanation:

In thermodynamics, the internal energy of a system is expressed in terms of pairs of conjugate variables such as temperature and entropy or pressure and volume. In fact, all thermodynamic potentials are expressed in terms of conjugate pairs. The product of two quantities that are conjugate has units of energy or sometimes power.

For a mechanical system, a small increment of energy is the product of a force times a small displacement. A similar situation exists in thermodynamics. An increment in the energy of a thermodynamic system can be expressed as the sum of the products of certain generalized "forces" that, when unbalanced, cause certain generalized "displacements", and the product of the two is the energy transferred as a result. These forces and their associated displacements are called conjugate variables. The thermodynamic force is always an intensive variable and the displacement is always an extensive variable, yielding an extensive energy transfer. The intensive (force) variable is the derivative of the internal energy with respect to the extensive (displacement) variable, while all other extensive variables are held constant.

The thermodynamic square can be used as a tool to recall and derive some of the thermodynamic potentials based on conjugate variables.

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