The complex [M(η6
-C6H6)(CO)2]2 obeys 18 electron rule and has one metal- metal
double bond. Predict M and sketch the probable structure of the complex.
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Answer:
CHAPTER 10: COORDINATION CHEMISTRY II: BONDING
10.1 a. Tetrahedral d6
, 4 unpaired electrons
b. [Co(H2O)6]
2+, high spin octahedral d7
, 3 unpaired electrons
c. [Cr(H2O)6]
3+, octahedral d 3
, 3 unpaired electrons
d. square planar d7
, 1 unpaired electron
10.2 a. [M(H2O)6]
3+ with 1 unpaired electron. d1
:
M = Ti
b. [MBr4]
–
with the maximum number of unpaired electrons (5).
M3+ with 5 d electrons: M = Fe
3–. The strong field cyano lig and favors
lo
d. [M(H2O)6]
2+
Explanation:
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