The compound that provides a carboxylic acid, upon treatment with br2 / naoh followed by acidification, is.
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Explanation:
The haloform reaction is a chemical reaction where a haloform (CHX3, where X is a halogen) is produced by the exhaustive halogenation of a methyl ketone (RCOCH3, where R can be either a hydrogen atom, an alkyl or an aryl group), in the presence of a base.[1][2][3] The reaction can be used to transform acetyl groups into carboxyl groups or to produce chloroform (CHCl3), bromoform (CHBr3), or iodoform (CHI3).
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only methyl ketones can produce carboxylic acid upon treatment with Br2 NaOH followed by acidification .
Explanation:
The reaction is known as haloform reaction .
The following steps takes place which conversion :
- –CH3 on a methyl ketone is converted to a trihalomethyl group.
- This decent leaving group allows the carbonyl to undergo a nucleophilic acyl substitution reaction with the NaOH already present in the reaction.
- loss of proton as carboxylic group is acidic ,
- acidification will stablize carboxylate ion to carboxylic acid .
To summarize alpha-halogenation is used to convert a methyl ketone into carboxylic acid .
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