The compound which does not undergo haloform reaction is
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alcohols: in case of primary alcohols only ethanol can give haloform test other primary alcohols do not. In alcohols beta carbon must be methyl group.
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The haloform reaction is the reaction of a methyl ketone with chlorine, bromine, or iodine in the presence of hydroxide ions to give a carboxylate ion and a haloform.
If you are trying to identify a compound, from a list, which does or does not undergo the reaction, you need to identify the methyl ketones and look for the R–CO–CH3 grouping.
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