The concentration of sucrose solution which is
isotonic with 0.02 M solution of Na, SO4 (assume
complete dissociation) at 30°C is
(1) 0.04 M
(2) 0.02 M
(3) 0.06 M
(4) 0.08 M
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Given: 0.02 M solution of sodium sulfate and it is isotonic with sucrose solution.
To find: We have to find the concentration of sucrose solution.
Solution:
As the sodium sulfate solution and the sucrose solution are isotonic so, they have the same osmotic pressure.
Sodium sulfate dissociate as-
The vant hoff factor, i=2+1
i=3
The osmotic pressure of sodium sulfate is as follows-
π=0.02×3×RT
The osmotic pressure of sucrose is as follows-
π=xRT
Here x is the concentration of sucrose solution.
Now we can write-
So, the concentration of sucrose solution is 0.06M.
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