The coulombs required for the oxidation of two mole of h2o to o2 are
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1 mol of H2O will give one atom of O Charge on O = – 2Electricity required =n F= 2 × 96487 Coulombs= 192974 Coulombs= 1.93 × 105 Coulombs
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2H2O→4H+O2+4e−
Q=4F
=4×96500Cmol−1
=38600cmol−1
(b) Zn is oxidized and Ag2O is reduced to Ag
E0cell=E0Ag+/Ag−E0zn2+/zn
=[0.344−(−0.76)V]V
=1.104V
AG0=−nFE0cell
=−2×96500cmol−1×1.10V
=−213×105Jmol−1
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