The cyclic integral of (δQ−δW) for a process is positive negative zero or unpredictable
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as per first law of thermodynamics we know that
now for a cyclic process if we apply the first law
we know that for all cyclic process initial and final state is always same
also we know that change in internal energy is a state function and depends only on initial and final state
so here for all cyclic integral we can say
so we have
so it must be zero for all cyclic integrals
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Answer:
only for cyclic process it iz zero but for for a process it is unpredictable, it may be +ve -ve or 0
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