The degree of hardness of sample of water containing 27.2 mg of CaSO4 per Kg of water is
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What is the degree of hardness of a sample of water containing 24 mg of MgSO
4
(mol. mass 120) per kg of water?
Medium
Solution
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Correct option is C)
Given, 1 kg of water contains 24 mg of MgSO
4
.
So 1 kg=1000 g of water.
1 million grams of water =1000×1000 g contains 24 mg×1000=24 g of MgSO
4
1 mole of MgSO
4
=1 mole of CaCO
3
120 g of MgSO
4
=100 g of CaCO
3
24 g of MgSO
4
=(x) g of CaCO
3
So, x=
120
24×100
=20
So, degree of hardness =20 ppm
The degree of hardness of water sample is 147 ppm
Explanation:
The hardness of water is the concentration of multivalent cations
In 1 lit of water
Wt of CaSO₄ = 200 mg = 0.2 gram
Molecular weight of CaSO₄= 136
Valency = 2
We know that
Equivalent Weight = Molecular Weight/Valency
Now,
Gram equivalents of CaSO₄ = Gram equivalents of CaCO₃
Weight of CaSO₄/Equivalent Weight of CaSO₄= Weight of CaCO₃/Equivalent weight of CaCO₃
or, 0.2/(136/2) = Weight of CaCO₃/(100/2)
or, 0.2/68 = Weight of CaCO₃/50
or, Weight of CaCO₃ = (0.2/68) × 50
= 0.147 gram
= 147 mg
Thus, the hardness as of CaCO₃ = 147 mg/lt = 147 ppm
Therefore, the degree of hardness of water sample = 147
Hope this answer is helpful.