the density of gas molecular mass=60 at critical point is 0.8g/cm3. if Tc=487K. The vandewaal gas constant 'a' is
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Vc=0.8060=75cm3mol−1; b=3Vc=25cm3mol−1=0.025Lmol−1
∴Tc=27Rb8a
8214×105=27×0.0821×0.0258×a
⇒a=3.375.
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