Question

The difference between simple complex and compound words

Answer 1

A compound sentence has more than one independent clause. ... Acompound-complex sentence has more than one independent clause and at least one dependent clause.
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Answer 2

Simple words: These expressions are the basic form of words which cannot  be further simplified, or say broken into- ‘morphemes’. Example: fire, joke, quick.

Compound words: These type of words have two or more words in them which are conjoined to generate a different meaning from the expressions. Example: dog house (open form), Firefly (closed form), over-the-counter (hyphenated).  

Complex words: These kind of words contain one base, or say root, and one or more affix (es). To understand we can say that they possess multiple morphemes. Example: quicker (quick+er), disestablishment (dis+establishment).

I hope the definitions and examples illustrated above may help you resolve your query.