The drain cleaner drainer contains small bits of aluminium which reacts with caustic soda to form H2 .
Volume of hydrogen released at 20°C and 1bar when 0.15 gm of aluminium reacts caustic soda is ?
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abhi178
abhi178 Genius
Al react with caustic soda to produce dihydrogen. reaction will be
2Al + 2NaOH + 2H2O -->2NaAlO2 + 3H2
here we see that, 2 mol of Al produce 3 mole of H2
∴ 2 × 27 g of Al produce 3 × 2 g of H2 .
∴ 54 g of Al produce 6g of H2.
∴ 1 g of Al produce 6/54 = 1/9 g of H2.
∴ 0.15g of Al produce 0.15/9 g of H2
so, number of mole of H2 produce = weight of HE produce/molar weight of H2
= (0.15/9)/2
= 0.15/18 = 0.00833 mol
now, use formula, PV = nRT
Here, P = 1 bar or 0.987 atm
T = 20°C or 293K
n = 0.00833 mol
R = 0.0821 atm dm³/K/mol
V = ?
V = 0.00833 × 0.0821 × 293/0.987
= 0.203 dm³
we know, 1 dm³ = 1000 mL
so, Volume of H2 = 1000× 0.203mL = 203mL
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