the group of lines in vibrational rotational spectrum fir which the successive j energy level is -1 are called as
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The group of lines in the vibrational rotational spectrum for which the successive j energy level is -1 are called rotational absorption lines.
Explanation:
- In Vibrational energy states, the rotational motion of a diatomic molecule can be discussed by the use of a rigid-rotor model.
- The real molecules are not rigid, however, the two nuclei are in a constant vibrational motion relative to one another.
- In rotational energy, the available kinetic energy is associated mainly with the rotational motion of molecules.
- Vibrational energy is the oscillatory motion of atoms or groups of atoms within a molecule (potential energy ↔ kinetic energy exchange).
- Electronic energy is energy that is stored as potential energy in excited electronic configurations.
- The quantum number J is the total angular momentum.
- There are three independent moments of inertia, where two are independent quantum numbers
- The J = 0 → J = 1 rotational absorption line will occur at wavelength in and at m in .
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