the half life period of a 1st order reaction is 30min calculate the time required to be completed in 25% completed
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For the first-order reaction, the relationship between the half-life period and the rate constant is
k=t1/20.693=300.693=0.0231min−1.
The rate law expression is k=t2.303log(a−x)a.
Substitute values in the above expression.
0.0231=702.303log(a−x)a
log(a−x)a=0.7021
(a−x)a=5.036
aa−x=5.0361=0.2
Thus, the percentage of the reactant remaining after 70 min will be 20%.
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