the hamiltonian operator for H2+in the borne Oppenheimer approximation is
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The application of the Born–Oppenheimer approximation leads naturally to the rigid rotor description of a molecule – we treat the rotation separately from the vibrational motion of the nuclei, which are considered later as a perturbation. ... The Hamiltonian for rotation is Hr=AJ2A+BJ2B+CJ2c.
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the hamiltonian operator for H2+in the borne Oppenheimer approximation is
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