the heat of combustion of ammonia and hydrogen 9.06 and 68.9 kilo calories respectively calculate the heat of formation of ammonia
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Answer:
heat of formation of ammonia is -94.29 Kcal
Explanation:
We are given that;
NH3+3/4O2→1/2N2+3/2H2O ΔH=−9.06 Kcal eq (i)
H2+1/2O2→H2O ΔH=−68. eq (ii)
Heat of formation is to be calculated for
1/2N2+3/2H2→2NH3
Multiply equation (ii) by 3/2
3/2H2+3/4O2→3/2H2O ΔH=−68.9×3/2=−103.35 Kcal
reverse equation (i)
1/2N2+3/2H2O→NH3+3/4H2 ΔH=+9.06Kcal
Now add both equations the terms on other sides will cancel out so finally we will get
1/2N2+3/2H2→NH3 ΔH=−103.35+9.06 ΔH=−94.29 Kcal
Hence the heat of formation of ammonia is -94.29 Kcal
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