the hydrogen gas released in this reaction of calcium and water does not catches fire but hydrogen gas released in the reaction of sodium and water catches instant fire because
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Metals like potassium and sodium react violently with cold water. In case of sodium and potassium, the reaction is so violent and exothermic that the evolved hydrogen immediately catches fire.
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Explanation: The Hydrogen gas evolved does not catches fire because then generated in this exothermic reaction is not enough to ignite the Hydrogen gas and it does not reaches to it's ignition temperature...
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