The important aromatic compound B which is prepared by heating the compound A with NaOH and CaO in the ratio 3:1 by mass .The compound B is also obtained by heating phenol with zinc dust. Answer the following:
a) Identify A and B.
b) what happened when the compound A is heated with methyl chloride in the presence of anhydrous AlCl3?
c) How would you convert acetylene into A?
d) How does A react with chlorine in the presence of sunlight?
e) Write down the two uses of A.
Answers
Answer:
Aromatic compounds are those chemical compounds (most commonly organic) that contain one or more rings with pi electrons delocalized all the way around them. In contrast to compounds that exhibit aromaticity, aliphatic compounds lack this delocalization. The term "aromatic" was assigned before the physical mechanism determining aromaticity was discovered, and referred simply to the fact that many such compounds have a sweet or pleasant odour; however, not all aromatic compounds have a sweet odour, and not all compounds with a sweet odour are aromatic. Aromatic hydrocarbons, or arenes, are aromatic organic compounds containing solely carbon and hydrogen atoms. The configuration of six carbon atoms in aromatic compounds is called a "benzene ring", after the simple aromatic compound benzene, or a phenyl group when part of a larger compound.
Not all aromatic compounds are benzene-based; aromaticity can also manifest in heteroarenes, which follow Hückel's rule (for monocyclic rings: when the number of its π electrons equals 4n + 2, where n = 0, 1, 2, 3, ...). In these compounds, at least one carbon atom is replaced by one of the heteroatoms oxygen, nitrogen, or sulfur. Examples of non-benzene compounds with aromatic properties are furan, a heterocyclic compound with a five-membered ring that includes a single oxygen atom, and pyridine, a heterocyclic compound with a six-membered ring containing one nitrogen atom.