The intermediate during the addition of HCl to propene in presence of peroxide is
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HCl and HI don't give hostile to Markovnikov expansion to alkene on the grounds that in chain response a few stages are endothermic.
The response with HCl is ominous as H-Cl bond is a lot more grounded than H-Br and response turns out to be moderate.
The chain responses are effective when propogation ventures in the response are exothermic.
An endothermic propogation steps will turn around the response and will break the chain.
The peroxide impact is just seen if there should be an occurrence of HBr.
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