The ionic size decreases in the order
a) K+> S2-> Sc3+> V5+ > Mn7+.
b) S2-> K+> Sc3+> V5+ > Mn7+
c) Mn7+ > V5+ > Sc3+ > K+>S2-
d) Mn7+ > V5+ > Sc3+ >S2- > K+
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In such a series, size decreases as the nuclear charge (atomic number) of the ion increases. The atomic numbers of the ions are S (16), Cl (17), K (19), and Ca (20). Thus, the ions decrease in size in the order: S2- > Cl– > K+ > Ca2+.
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