The Ligand (A) in brown ring complex (B) is obtainable from a lead compound (C) with a dense liquid (D) which concerts salts (E) into acid {F) Give structure and reaction
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In this compound, the nitrosyl ligand is positively charged, and iron is in a +1 oxidation state.
Now, iron has stable oxidation states +2 and +3. Nitrosyl, as a ligand, comes in many flavours, of which a negatively charged nitrosyl is one.
I see no reason why the iron doesn't spontaneously oxidise to +3 and reduce the NO to −1 to gain stability. But I don't know how to analyse this situation anyway. I think that there may be some nifty backbonding increasing the stability, but I'm not sure.
So, why is iron in +1 here when we can have a seemingly stable situation with iron in +3
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