Chemistry, asked by shahiddar78, 1 year ago

the mechanism of dehydration of an alcohol to give an alkene involves formation of​

Answers

Answered by Anonymous
3

it involves the formation of water.

Let's take an example,

C2H5OH — C2H4 + H2O.

here, ethyl alcohol is dehydrated in presence of sulphuric acid.


shahiddar78: no
Anonymous: y.
shahiddar78: formation of free radicals
shahiddar78: but in book there is no option for water
Anonymous: ok
shahiddar78: in book there is option carbanion ,carbens, free radicals, carbonium ions
Anonymous: ohh
Anonymous: sorry then
shahiddar78: hmm
shahiddar78: koye nahi
Answered by KaurSukhvir
0

Answer:

The mechanism of dehydration of an alcohol to give an alkene involves three steps:

  1. Protonation of alcohol
  2. Formation of carbocation
  3. Deprotonation

Explanation:

  • First step: The formation of protonated alcohol from the simple alcohol. The alcohol acts as a weak base because it has two lone pairs on the oxygen atom of (-OH) group. The alcohol reacts with strong acids such as HCl to form oxonium salt.

        CH₃CH₂-OH   +   H⁺   ⇄    CH₃CH₂-O⁺H₂

  • Second step: Protonated alcohol removes a water molecule from it, which leads to formation of a carbocation.

        CH₃CH₂-O⁺H₂       ⇄      CH₃CH₂⁺          +          H₂O

     Protonated alcohol              Primary carbocation

  • Third step: Ethylene carbocation is very reactive species. it easily removed proton and formed ethene molecule.

       H-CH₂-CH₂⁺    ⇄    CH₂=CH₂   +   H⁺

                                       alkene

Hence, the formation of alkene from the alcohol by dehydration.

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