the mechanism of dehydration of an alcohol to give an alkene involves formation of
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it involves the formation of water.
Let's take an example,
C2H5OH — C2H4 + H2O.
here, ethyl alcohol is dehydrated in presence of sulphuric acid.
shahiddar78:
no
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Answer:
The mechanism of dehydration of an alcohol to give an alkene involves three steps:
- Protonation of alcohol
- Formation of carbocation
- Deprotonation
Explanation:
- First step: The formation of protonated alcohol from the simple alcohol. The alcohol acts as a weak base because it has two lone pairs on the oxygen atom of (-OH) group. The alcohol reacts with strong acids such as HCl to form oxonium salt.
CH₃CH₂-OH + H⁺ ⇄ CH₃CH₂-O⁺H₂
- Second step: Protonated alcohol removes a water molecule from it, which leads to formation of a carbocation.
CH₃CH₂-O⁺H₂ ⇄ CH₃CH₂⁺ + H₂O
Protonated alcohol Primary carbocation
- Third step: Ethylene carbocation is very reactive species. it easily removed proton and formed ethene molecule.
H-CH₂-CH₂⁺ ⇄ CH₂=CH₂ + H⁺
alkene
Hence, the formation of alkene from the alcohol by dehydration.
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