The molar solubility of caf2(ksp = 5.3 1011) in 0.1 m solution of naf will be
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Thus the molar solubility of CaF2 is 5.3 × 10^-9 mol/L
Explanation:
Given data:
- K sp = 5.3 × 10^-11,
- C = 0.1 M
Solution:
CaF2 dissociates into Ca²+ and 2 F- ions.
Ca F2 ⇔ Ca²+ + 2 F-
For Na F ⇔Na + + F-
At equilibrium:
0. C. C
In solution, [F-] = (2s + C)
Due to common ion effect, [F-] ≈ C
Now, Ksp = [Ca²+] [F-]²
Ksp = s × C²
s = Ksp/C²
s = 5.3 × 10^-11 / (0.1)^2 = 5.3 × 10^-9 mol/L
Thus the molar solubility of CaF2 is 5.3 × 10^-9 mol/L
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