The mole fraction of glucose in its aqueous solution having 755 mm of Hg vapour pressure at 373K is (VP of H₂O at 100°C 760 mm of Hg)
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The expression for the relative lowering in the vapor pressure and the mole fraction of solute is
P
ΔP
=
N
n
For 1 L of solution
760
10
=
55.56
n
Thus, the number of moles of solute n=0.731
Thus, the mole fraction of solute =
55.56
0.731
=0.013
The molarity of the solution is
1
0.731
=0.731M
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