The pk of weak acid h a is 4.5 the ph of an aqueous buffer solution of a in which 50% of acid is ionized is
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ph =pka=4.5 ; this is because the ratio log [A^-]/[HA]=log o.5/0.5=0
hence, ph=pka in the formulla ph=pka+log [A^-]/[HA]
hence, poh= 14-ph=14-4.5=9.5
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