The potential energy function for the force between two atoms in a diatomic molecule is approximately given by u(x) a/x¹²- b/x⁶ , Where a and b are constants and x is the distance between the atoms . if the dissociation energy of the molecule is D = [U (x = ∞) -Uat equilibrium ] , D is [AIEEE 2010]
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Explanation :- U(x) = a/x¹² -b/x⁶
U(x= ∞ ) = 0
As F = -dU /dx = - [ 12a/x¹³ + 6b/x⁷]
At equilibrium , F = 0
- 12a/x¹³ = 6b/x⁷
- 12a/6b = x¹³/x⁷
- 2a/b = x⁶
- ∴ x⁶ = 2a/b
U at equiblirium = a/ (2a/b)² - b(2a/b)= -b²/4a
∴ D [ U (x= ∞ ) - U at equilibrium ] = b²/4a
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