The predominant product formed when propene reacts with nocl
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more electronegative than ClCl (albeit by a very small difference) but it should ideally dissociate as Cl+ClX+ and −NO−NO (similar to the dissociation of ClClin HOClHOCl). Moreover, due to the stronger bonding between NN and O,NO,N should also be pulling electrons even more tightly to itself due to the very electronegative OO by its side.
I was doing a problem on the electrophilic addition of NOClNOCl on alkene and ended by getting the wrong product (according to the book) because I took Cl+ClX+ and −NO−NO in the mechanism at the very beginning. Could someone explain?
I've attached pictures of what I have done and what the book has done too. Please correct me if I am wrong.
What I did:

I was doing a problem on the electrophilic addition of NOClNOCl on alkene and ended by getting the wrong product (according to the book) because I took Cl+ClX+ and −NO−NO in the mechanism at the very beginning. Could someone explain?
I've attached pictures of what I have done and what the book has done too. Please correct me if I am wrong.
What I did:

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