the pressure needed for the reaction co(g) + 2H2O (g) - CH3OH(l) is
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Answer:
The equilibrium constant is 26.
First, write the balanced chemical equation with an ICE table.
CO(g) + 2H₂(g) ⇌ CH₃OH(g)
I/mol·L⁻¹: 0.500; 0.100; 0
C/mol·L⁻¹: -
x
; -2
x
; +
x
E/mol·L⁻¹: 0.500 -
x
; 0.100 - 2
x
;
x
At equilibrium, [CO] = 0.15 mol/L = (0.500 -
x
) mol/L
So
x
= 0.500 – 0.15 = 0.35
Then
[
H
2
]
= (0.100 - 2
x
) mol/L = (0.100 – 2×0.35) mol/L = 0.30 mol/L
and
[
CH
3
OH
]
=
x
mol/L = 0.35 mol/L
K
eq
=
[
CH
3
OH
]
[
CO
]
[
H
2
]
2
=
0.35
0.15
×
0.30
2
= 26
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