The process in which the value of ∆u=0 ¿
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Answered by
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the question is not clear please clarify this again
Answered by
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The higher the temperature, the more motion a molecule can have, the more microstates it can assume, the more ways it can absorb heat to use for motion, and thus the more heat it needs to maintain that motion.
Δ
S
=
∫
∂
q
rev
T
≥
0
The change in entropy, is therefore the differential (change in) reversible heat flow at a specific temperature.
You know that for a closed system,
Δ
U
=
0
, so using the first law of thermodynamics:
Δ
U
=
q
rev
+
w
rev
=
0
Therefore...
q
rev
=
−
w
rev
=
−
(
−
P
Δ
V
)
≠
0
As a result, you really ought to have some nonzero value for entropy (as the third law of thermodynamics should suggest when you're not at absolute zero).
So if you really want a value for
Δ
S
of an ideal gas, you need a temperature, some heat flow, and you need a change in volume. Then just perform the above integral (with respect to the differential heat flow
∂
q
) to get:
Δ
S
=
q
rev
T
≥
0
Note that
Δ
S
>
q
T
when
q
is not reversible/efficient.
Δ
S
=
∫
∂
q
rev
T
≥
0
The change in entropy, is therefore the differential (change in) reversible heat flow at a specific temperature.
You know that for a closed system,
Δ
U
=
0
, so using the first law of thermodynamics:
Δ
U
=
q
rev
+
w
rev
=
0
Therefore...
q
rev
=
−
w
rev
=
−
(
−
P
Δ
V
)
≠
0
As a result, you really ought to have some nonzero value for entropy (as the third law of thermodynamics should suggest when you're not at absolute zero).
So if you really want a value for
Δ
S
of an ideal gas, you need a temperature, some heat flow, and you need a change in volume. Then just perform the above integral (with respect to the differential heat flow
∂
q
) to get:
Δ
S
=
q
rev
T
≥
0
Note that
Δ
S
>
q
T
when
q
is not reversible/efficient.
khushigupta9717:
i hope it is ur ans
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