Chemistry, asked by sunny137, 1 year ago

the radius of Na+ cation is less than that of Na atom.

Answers

Answered by vishagh
44
ATOMIC SIZE: Distance from the nuclius to the outermost electron.

Na⁺→Loss of one electron.
The atomic radius of Na⁺ is less than that of Na,because due to the loss of 1e ⁻,the inter electronic repulsion by the electrons in the inner shell decreases.

As the interelectronic repulsion decreases, the attraction between the nuclei  and the outermost electron increases,leading to the decrease in the atomic size.

NOTE:
1.
Size of cation is always smaller than the parent atom.
2.Size of anioin is larger than the parent atom.

vishagh: Hope it helped.comment in case of doubt.
Answered by kvnmurty
41
Na:  1s2 2s2  2p6  3s1 ....
     So the outermost shell    n = 3 for the outermost electron.

For Sodium ion:  Na+:   the outermost orbit is n = 2 only.

Thus the radius of Na+ is less than that of Sodium, as the shell 3 is not present in it.

Usually the radius of a cation is less than that of a neutral atom.

kvnmurty: click on red heart thanks above pls
vishagh: Sir is less interelectronic repulsion a valid reason,incase the cation and the parent atom have same no of shells?
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