The rate equation for a first order reaction is given by . A straight line with positive slope is obtained by plotting.
initial concentration of reactant,
concentration of reactant at time, t
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For a first-order reaction, a plot of the natural logarithm of the concentration of a reactant versus time is a straight line with a slope of −k. For a second-order reaction, a plot of the inverse of the concentration of a reactant versus time is a straight line with a slope of k.
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