The ratio of volume of gases obtain at anode when aq. NaCl and aq. Na2SO4 is electrolysed, connected in series is respectively
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The ratio of volume of gases obtain at anode when aq. NaCl and aq. Na2SO4 is electrolysed, connected in series is respectively
Explanation:
Electrolysis of aq. NaCl
Cathode Anode
Na⁺ U⁻
H₂O H₂O
∴ 2U⁻ ---------> U₂ + 2e U₂(anode)
2e + H₂O ---------> H₂ +2OH
2NaCl + 2H₂O ---------> U₂+ H₂ + 2NaOH
∴ 2F ' current
∴ the ratio is 2:1
U₂ : O₂
For NaSO₄
Cathode Anode
Na⁺ SO₄
H₂O H₂O
Anode :
∴ H₂O ---------> 2H⁺ + 1/2 O₂ + 2e
2e + 2H₂O ---------> H₂ + 2U⁻
H₂O ---------> H⁺ + 1/2 O₂ (1/2 O₂ -anode)
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