The reaction for tarnish formation due to contact with hydrogen sulphide.
2Ag(s) + H2
S(g) → Ag2
S(s) + H2(g) and the above tarnish can be removed by using Al metal as
2 23 23 6 Al + →+ Ag S S Ag Al
The above two reactions appears to be a displacement reactions. But ‘Ag’ is less reactive than ‘H’
in reactivity series. Then what might be the reason. [ ]
i) ‘Ag’ can displace ‘H’ under certain conditions even though it is less reactive
ii) Ag cannot react directly with H2
S to displace ‘H’ from it.
iii) ‘Ag’ first oxidised to its oxide and then it reacts with H2
S to form Ag2
S
iv) The formation of Ag2
S is possible by a decomposition reaction.
a) i, ii, iii only b) ii, iii only c) ii, iii, iv only d) All
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option (a)
i, ii, iii only
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