The reaction that does not give benzoic acid as
the major product is
CH,OH
KMnO/H
(1)
CH,OH
K,Cr,O,
(2)
COCH,
(3)
(i) NaOCI
(II) H,09
СН,ОН
PCC
(4)
Pyridinium
chlorochromate
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OPTION 4 Pyridinium chlorochromate
Answer. The reaction given in option 4 does not produce benzoic acid as the major product. KMnO4 is a very strong oxidizing agent so it oxidizes alcohol directly to carboxylic acid.It cannot be stopped at the aldehyde/ketone stage.
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