The reason for higher pkb value of aniline compared to that of methylamine is
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In aniline, the lone pair of electrons on the N atom is delocalised over the benzene ring. ... Therefore, aniline is a weaker base than methylamine. Hence, its pKb value is higher than that of methylamine. (ii) Being more basic than water, methylamine accepts a proton from water-liberating OH− ions.
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(i) In aniline, the lone pair of electrons on the N atom is delocalised over the benzene ring. ... Therefore, aniline is a weaker base than methylamine. Hence, its pKb value is higher than that of methylamine.
(ii) Being more basic than water, methylamine accepts a proton from water-liberating OH− ions.
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