The separation of lines in the rotational spectra of the HCl molecule was found to be
20.6 cm-1. Calculate the internuclear distance.
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are higher in energy than the pure vibrational transition and form the R-branch. Notice that because the ΔJ=±0 transition is forbidden there is no spectral line associated with the pure vibrational transition. Therefore there is a gap between the P-branch and R-branch, known as the q branch
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