The shape of the molecules is based on the VSEPR theory. Give the salient features of this theory
Answers
Yeah you are absolutely right.
The shape of the molecules is based on VSPER theory [ Valency Shell Electron Pair Repulsion ] Theory.
Let us see some of the Salient features of this theory and some examples,
➠ The shape of the molecule and the bond angle depends on the repulsion between electron pairs present in valency shell of central atom.
➠ Electron in central atoms are of two types
⠀⠀⠀⠀⠀⠀❆ Bond Pair ❆
⠀⠀⠀⠀⠀⠀❆ Lone pair ❆
➠ Pair of electrons in the valency shell should repel one another since they have negative charge in their valency cloud.
➠ The extent of repulsion between also depends on the Electronegativity difference between two bonded atoms.
➠ The repulsion between electron pair is given as
➠ Repulsion between 2 single bonds will be lesser than 2 double bonds.
➠ According to VSEPR Theory electron pair will be arranged around the central atom with least possible repulsions {i.e} Max possible gap should be maintained.
➠ A multiple bond is treated as if it has single electron pair.
✧ Bond Pair - Has No lone pair of electrons ✧
✧ Lone Pair - Has left lone pair of electrons ✧
➠ In the given VSPER molecule H will involve single bond, Halogen will involve Single bond, O will involve double bond & N will involve triple bond
-These are some of the salient features of VSPER theory.
Some of the shapes and Bond angles of VSPER theory are,
1.) Linear - 180°
2.) Trigonal Planar - 120°
3.) Tetrahedral - 109.28°
4.) Trigonal Bipyramidal -180°,120°,90°
5.) See saw shape = >120° and >90°
6.) T shaped - < 90°
7.) Octahedral - 90°
8.) Square planar - 90°
9.) Pentogonal Bipyrimdal - 90°&72°
10.) Disorted octahedral - all angles ≠ 90°
ℌope ℑt ℌelps
Thanks for asking :)